ARTÍCULO
TITULO

Evaluation of Cu/activated carbon and Cu/SiO2 aerosil catalysts on ethanol reform

Rita de Cássia Colman    
Anderson Alex de Almeida    
Nádia Regina Camardo Fernandes Machado    
José Carlos de Souza (Author)    

Resumen

New ways to produce hydrogen, thought to be the ideal fuel, have been studied and aim at a not-pollutant fuel. Ethanol reform is based on a simple reaction with many advantages for various countries, such as Brazil, where ethanol is produced on a large scale. Within a broader analysis, Cu/activated carbon catalysts with copper concentration of 5% w/w and Cu/SiO2 aerosil catalysts with copper concentration of 2 and 5% w/w have been prepared by wet impregnation. Decrease in programmed temperature was undertaken. Results of catalytic tests indicated that Cu/activated carbon catalysts probably contain sulfur and this explains why catalyst yields have been diminished. Occurrence may be explained because the results of the supported catalysts do not maintain a standard level and vary randomly with the surface area. Results of Cu/SiO2 aerosil catalysts show that a conversion reduction occurs with the rise of support surface area and that copper concentration do not cause great changes.

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