ARTÍCULO
TITULO

Synthesis of Camelina oil ethyl esters as components of jet fuels

Sergii Boichenko    
Stepan Zubenko    
Sergii Konovalov    
Anna Yakovlieva    

Resumen

Unrefined Camelina oil was transesterified on an alkaline catalyst with the application of commercial fuel ethanol of high hygroscopicity. It was shown that the rise of moisture content in alcohol up to 1 % leads to the low output of ethyl esters. The technological scheme of production of a pilot batch of Camelina oil ethyl esters in laboratory conditions was proposed. The scheme includes: preparation of catalyst solution, transesterification of oil with ethanol, sedimentation, alcohol stripping, separation, washing, drying and filtration. This allows obtaining products with the content of esters of about 92?93.5 %. The chromatographic analysis of the products of Camelina oil transesterification was done. The obtained products contain mostly unsaturated esters of fatty acids with the carbon chain length of 18 atoms.The comparative analysis of the fatty acid composition of the obtained ethyl esters of Camelina oil and ethyl esters of rapeseed oil, studied during previous researches of the authors, was done. The fatty acid composition allows forecasting lower viscosity, pour and freezing point of Camelina ethyl esters compared to rapeseed oil ethyl esters. The proposed assumption was proved by experimental data of researches of the basic physical-chemical characteristics of methyl and ethyl esters of rapeseed and camelina oils. The obtained experimental data proves the perspectiveness of using products of Camelina oil transesterification as components of jet fuels. In the future, compounding of synthesized fatty acid ethyl esters of Camelina oil with jet fuels will allow obtaining biofuels with improved quality parameters compared to biofuels with rapeseed oil esters

 Artículos similares

       
 
Maria Vanessa Souza Oliveira, Patrícia Caroline Molgere Da Rós, Silvana Mattedi, Heizir Ferreira Castro, Cleide Mara Faria Soares, Álvaro Silva Lima     Pág. 445 - 451
Enzymatic transesterification from non-edible vegetable oil (babassu oil) and ethanol is provided. A set of seven experiments featuring a full 22 factorial design with three central points and different combinations of molar ratio and temperature as inde... ver más

 
Camila da Silva, Gustavo Borges, Fernanda Castilhos, José Vladimir Oliveira, Lúcio Cardozo-Filho     Pág. 185 - 192
This work reports the production of fatty acid ethyl esters (FAEE) from the transesterification of soybean oil in supercritical ethanol in a continuous catalyst-free process using different reactor configurations. Experiments were performed in a tubular ... ver más

 
Polyana Batoqui França, Ana Carolina Aguiar, Paula Fernandes Montanher, Marcela Boroski, Nilson Evelázio de Souza, Jesuí Vergílio Visentainer     Pág. 221 - 225
One of the most consumed freshwater fish in South America is Nile tilapia. The present study examined the effects of flaxseed oil (FO), source of alfa-linolenic acid (LNA), on the total lipid composition and polyunsaturated fatty acid, n-6 and n-3 PUFA, ... ver más

 
Sergejus Lebedevas, Galina Lebedeva, Violeta Makareviciene, Prutenis Janulis and Egle Sendzikiene     Pág. 217 - 223
Revista: ENERGY AND FUELS

 
Francisco F. P. Santos, Leonardo J. B. L. Matos, Sueli Rodrigues and Fabiano A. N. Fernandes     Pág. 4116 - 4120
Revista: ENERGY AND FUELS