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ARTÍCULO
TITULO

Adequacy of isotherm adsorption of black 5 reactive dye for crosslinked chitosan microspheres

Irene Yukiko Kimura    
Valfredo Tadeu Favere    
Amarildo Otavio Martins    
Viviane Aparecida Spinelli    
Atche Josué (Author)    

Resumen

Chitosan microspheres with average diameter 1.03 ± 0.06 mm and degree of deacetylation of 72.5% were employed as adsorbent for reactive dye black 5. Chitosan was characterized through infrared spectroscopy (IR), 13C NMR spectrum and deacetylation degree (DD%), and crosslinked with glutaraldehyde 2.5% (w/v) to increase its resistance in acid medium. Corresponding isotherms were obtained in acid and alkaline solutions. Experimental data were fitted by Langmuir?s, extended Freundlich?s and Nernst?s isotherms. Adsorption was more effective in acid medium and adjusted better the Langmuir?s isotherm