Efeito de nanotubos de carbono sobre as propriedades térmicas e mecânicas de biopolímeros
Resumo
Nanotubos de carbono (CNT) têm sido amplamente estudados no desenvolvimento de nanocompósitos poliméricos devido às suas elevadas propriedades térmicas e mecânicas. Entretanto os biopolímeros, classe que também ganhou grande interesse em busca de materiais sustentáveis, apresentam propriedades inferiores aos polímeros tradicionais, o que pode limitar sua aplicação. Desta forma, o objetivo desse artigo consistiu na realização de uma revisão de literatura, a fim de determinar o atual estado da arte dos nanocompósitos de CNT em matrizes de biopolímeros. Com base nesse levantamento bibliográfico pode-se dizer que de maneira geral, sistemas com adequada dispersão demonstram uma maior resistência térmica que as matrizes puras, bem como levam ao aumento das propriedades mecânicas favorecidas pela maior rigidez do sistema.
Referências
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CAPEK, I. Dispersions, novel nanomaterial sensors and nanoconjugates based on carbon nanotubes. Advances in Colloid and Interface Science, [S.l.], v. 150, p. 63-89, 2009. DOI: 10.1016/j.cis.2009.05.006.
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GOGOTSI, Yury. Nanotubes and Nanofibers. Boca Raton, FL: CRC Taylor & Francis, 2006.
GROSS, R. A.; KALRA, B. Biodegradable Polymers for the Environment. Science, [S.l.], v. 297, n. 5582, p. 803-807, 2002. DOI: 10.1126/science.297.5582.803.
HANDBOOK of materials for nanomedicine. Pan Stanford Publishing, v.1, 2005.
KIM, H. S.; CHAE, Y. S.; PARK, B. H.; YOON, J. S.; KANG, M.; JIN, H. J. Thermal and electrical conductivity of poly(L-lactide)/multiwalled carbon nanotube nanocomposites. Current Applied Physics, [S.l.], v. 8, p. 803-806, 2008. DOI: 10.1016/j.cap.2007.04.032.
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KUAN, C. F.; KUAN, H. C.; MA, C. C. M.; CHEN, C. H.; Mechanical and electrical properties of multi-wall carbon nanotube/poly(lactic acid) composites. Journal of Physics and Chemistry of Solids, [S.l.], v. 69, p. 1395-1398, 2008a. DOI: 10.1016/j.jpcs.2007.10.060.
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MA, Y.; ZHENG, Y.; WEI, G.; SONG, W.; HU, T.; YANG, H.; XUE, R. Processing, Structure, and Properties of Multiwalled Carbon Nanotube/Poly(hydroxybutyrate-co-valerate) Biopolymer Nanocomposites. Journal of Applied Polymer Science, [S.l.], v. 125, p. 620-629, 2012. DOI: 10.1002/app.35650.
MALIKOV, E. Y.; MURADOV, M. B.; AKPEROV, O. H.; EYVAZOVA, G. M.; PUSKÁS, R.; MADARÁSZ, D.; NAGY, L.; KUKOVECZ, A.; KÓNYA, Z. Synthesis and characterization of polyvinyl alcohol based multiwalled carbon nanotube nanocomposites. Physica E, [S.l.], v. 61, p. 129-134, 2014. DOI: 10.1016/j.physe.2014.03.026.
MALLAKPOUR, S.; ABDOLMALEKI, A.; BORANDEH, S. L-Phenylalanine amino acid functionalized mutli walled carbon nanotube (MWCNT) as a reinforced filler for improving mechanical and morphological properties of poly(vinyl alcohol)/ MWCNT composite. Progress in Organic Coatings, [S.l.], v. 77, p. 1966-1971, 2014. DOI: 10.1016/j.porgcoat.2014.07.005.
MALLAKPOUR, S.; DINARI, M. Biomodification of Cloisite Na+ with L-Methionine Amino Acid and Preparation of Poly(vinyl alcohol)/Organoclay Nanocomposite Films. Journal of Applied Polymer, [S.l.], v. 124, p. 4322-4330, 2012. DOI: 10.1002/app.35540.
MONIRUZZAMAN, M.; WINEY, K. I. Polymer Nanocomposites Containing Carbon Nanotubes. Macromolecules, [S.l.], v. 39, n. 16 p. 5194-5205, 2006. DOI: 10.1021/ma060733p.
MUBARAK, N. M.; ABDULLAH, E. C.; JAYAKUMAR, N. S.; SAHU, J. N. An overview on methods for the production of carbon nanotube. Journal of Industrial and Engineering Chemistry, [S.l.], v. 20, p. 1186-1197, 2014. DOI: 10.1016/j.jiec.2013.09.001.
NAFFAKH, M.; DÍEZ-PASCUAL, A. M.; MARCO, C.; ELLIS G. J.; GÓMEZ-FATOU, M. A. Opportunities and challenges in the use of inorganic fullerene-like nanoparticles to produce advanced polymer nanocomposites. Progress in Polymer Science, [S.l.], v. 38, p. 1163-1231, 2013. DOI: 10.1016/j.progpolymsci.2013.04.001.
OJIJO, V.; RAY, S. S. Processing strategies in bionanocomposites. Progress in Polymer Science, [S.l.], v. 38, p. 1543-1589, 2013. DOI: 10.1016/j.progpolymsci.2013.05.011.
OKAMOTO, M.; JOHN, B. Synthetic biopolymer nanocomposites for tissue engineering scaffolds. Progress in Polymer Science, [S.l.], v. 38, p. 1487-1503, 2013. DOI: 10.1016/j.progpolymsci.2013.06.001.
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REDDY, M. M.; VIVEKANANDHAN, S.; MISRA, M.; BHATIA, S. K.; MOHANTY, A. K. Bio-nanocomposites for food packaging applications. Progress in Polymer Science, [S.l.], v. 38, p. 1653-1689, 2013. DOI: 10.1016/j.progpolymsci.2013.05.006.
RHIM, J. W.; PARK, H. M.; HA, C. S. Bio-nanocomposites for food packaging applications. Progress in Polymer Science, [S.l.], v. 38, p. 1629-1652, 2013. DOI: 10.1016/j.progpolymsci.2013.05.008.
ROSA, D. S.; LOTTO, N. T.; LOPES, D. R.; GUEDES, C. G. F. The use of roughness for evaluating the biodegradation of poly-ß-(hydroxybutyrate) and poly-ß-(hydroxybutyrate-co-ß-valerate). Polymer Testing, [S.l.], v. 23, p. 3-8, 2004. DOI:10.1016/S0142-9418(03)00042-4.
SAHOO, N. G.; RANA, S.; CHO, J. W.; LI, L.; CHAN, S. H. Polymer nanocomposites based on functionalized carbon nanotubes. Progress in Polymer Science, [S.l.], v. 35, p. 837-867, 2010. DOI: 10.1016/j.progpolymsci.2010.03.002.
SANCHEZ-GARCIA, M. D.; LAGARON, J. M.; HOA, S. V. Effect of addition of carbon nanofibers and carbon nanotubes on properties of thermoplastic biopolymer. Composites Science and Technology, [S.l.], v. 70, p. 1095-1105, 2010. DOI: 10.1016/j.compscitech.2010.02.015.
SELIGRA, P. G.; NUEVO, F.; LAMANNA, M.; FAMÁ, L. Covalent grafting of carbon nanotubes to PLA in order to improve compatibility. Composites: Part B, [S.l.], v. 46, p. 61-68, 2013. DOI:10.1016/j.compositesb.2012.10.013.
SEPAHVAND, R.; ADELI, M.; ASTINCHAP, B.; KABIRI, R. New nanocomposites containing metal nanoparticles, carbon nanotube and polymer. Journal of Nanoparticles Research, [S.l.], v. 10, p. 1309-1318, 2008. DOI 10.1007/s11051-008-9411-2.
SOUZA FILHO, A. G. de; FAGAN, S. B. Funcionalização de nanotubos de Carbono. Química Nova, São Paulo, v. 30, n. 7, p. 1695-1703, 2007.
SPITALSKY, Z.; TASIS, D.; PAPAGELIS, K.; GALIOTIS, C. Carbon nanotube-polymer composites: Chemistry, processing, mechanical and electrical properties. Progress in Polymer Science, [S.l.], v. 35, p. 357-401, 2010. DOI: 10.1016/j.progpolymsci.2009.09.003.
STEFOV, V.; NAJDOSKI, M.; BOGOEVA-GACEVA, G.; BUZAROVSKA, A. Properties assessment of multiwalled carbon nanotubes: A comparative study. Synthetic Metals, [S.l.], v. 197, p. 159-167, 2014. DOI:10.1016/j.synthmet.2014.09.011.
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Publicado
2016-07-15
Como Citar
PEDROSA, Maria Clara Guimarães; MENEZES, Lívia Rodrigues de; SILVA, Emerson Oliveira da.
Efeito de nanotubos de carbono sobre as propriedades térmicas e mecânicas de biopolímeros.
Acta Scientiae et Technicae, [S.l.], v. 4, n. 1, jul. 2016.
ISSN 2317-8957.
Disponível em: <http://www.uezo.rj.gov.br/ojs/index.php/ast/article/view/90>. Acesso em: 05 jun. 2024.
doi: https://doi.org/10.17648/uezo-ast-v4i1.90.
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