Sourwater treatment by fenton process and its effect on phytotoxicity with <i>Lactuca sativa

  • Thiago Atsushi Takashina Universidade Federal do Paraná
  • Celia Regina Granhen Tavares Universidade Estadual de Maringá
  • Marcos Rogério Mafra Universidade Federal do Paraná
  • Mônica Beatriz Kolicheski Universidade Federal do Paraná
  • Luciana Igarashi-Mafra Universidade Federal do Paraná
Keywords: petroleum effluent, advanced oxidative process, total phenols, bioassays, experimental design.

Abstract

In this work, degradation of stripped sourwater by Fenton´s oxidation process was investigated by a central composite design and response surface methodology. The effects of initial concentrations of H2O2 and Fe2+ on the total phenols degradation was studied in a batch reactor. The optimum total phenols degradation was 92% achieved within an H2O2 concentration of 4.4 g L-1 and iron concentration of 162 mg L-1. The mathematical kinetic model adequately represented the experimental results. The results indicated that the Fenton oxidation rate (1/m) and removal efficiency (1/b) were more dependent on iron concentration than H2O2 concentration. After the Fenton process, the sourwater presented a seed germination rate (L. sativa) above 80%, indicating reduced phytotoxicity of the treated effluent. It was also observed that the H2O2 concentration significantly affected the inhibition concentration (IC50).

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Author Biographies

Thiago Atsushi Takashina, Universidade Federal do Paraná
Departamento de Engenharia Química
Celia Regina Granhen Tavares, Universidade Estadual de Maringá
Departamento de Engenharia Química
Marcos Rogério Mafra, Universidade Federal do Paraná
Departamento de Engenharia Química
Mônica Beatriz Kolicheski, Universidade Federal do Paraná
Departamento de Engenharia Química
Luciana Igarashi-Mafra, Universidade Federal do Paraná
Departamento de Engenharia Química
Published
2019-07-04
How to Cite
Takashina, T. A., Tavares, C. R. G., Mafra, M. R., Kolicheski, M. B., & Igarashi-Mafra, L. (2019). Sourwater treatment by fenton process and its effect on phytotoxicity with <i&gt;Lactuca sativa. Acta Scientiarum. Technology, 41(1), e41288. https://doi.org/10.4025/actascitechnol.v41i1.41288
Section
Chemical Engineering

 

0.8
2019CiteScore
 
 
36th percentile
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0.8
2019CiteScore
 
 
36th percentile
Powered by  Scopus