Porosity-to-Cement Index Controlling the Strength and Microstructure of Sustainable Crushed Material-Cemented Soil Blends
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Definition of the Porosity, Dry Unit Weights, RT, Cement, and Moisture Content
2.3. Preparing the Specimens for the qu and qt Tests
2.4. Chemical Microanalysis and EDX Tests
3. Optimization and Design Parameters for Determining and Estimating the Strength
4. Analysis of the Laboratory Data and Discussions
4.1. Influence of the Porosity-to-Volumetric Cement Content Index (η/Civ) on the Unconfined Compressive and Splitting Tensile Strength, Using the Optimized Parameters bo and k
- -
- There is an increase in qu and qt with the increase in the cement percentage and with the increase of the dry unit weight of the molding, defined in Table 4;
- -
- Since there is a fall of qu and qt as a function of RT, Figure 2, Figure 3 and Figure 4 also show this decrease as a function of the percentages RT = 5% (Figure 2), RT = 15% (Figure 3) and RT = 30% (Figure 4), where the constant Aq decreases both for qu and for qt with the increase of RT. The value of Aq decreases by 8% from 5 to 30% of RT in the compression tests. For the tensile tests, the decrease in Aq was 12% from 5 to 30% of RT.
- -
- Although Aq, qu, and qt decrease from 5 to 30% of RT, reusing the tile residue is vital. It is essential to reduce and reuse the volume of waste discarded from civil construction. Reusing this type of waste (RT) is intended to extend a product’s life on civil constructions: in pavements, for example. Products in this category must indicate how many production cycles they can pass without affecting their main characteristics.
4.2. Empirical Relationships between qu and qt
4.3. Dosage Equations for Estimating and Predicting the Strength of Roof Tile-Soil Mixes with Cement
4.4. Chemical Microanalysis Results
5. Concluding Remarks
- 1.
- The objective of this article was to verify the impact of the porosity/cement ratio on the mechanical resistance of RT-soil-cement mixtures. When verifying the results, it is evident that the porosity/cement ratio adjusted to an exponent of 0.29 controls not only the unconfined compression but also the split tensile and the empirical relationship between these two;
- 2.
- The increase in the molding dry unit weight and the consequent reduction in the mixtures’ porosity, significantly influenced the values obtained for the split tensile and compressive strength. This influence was visible in the inclination of the lines in the main effects graphs (see Figure 5);
- 3.
- A correlation of qu and qt with the index resulted in excellent relations with coefficients of determination (R2) between 93% and 98%. Even with the existence of variability between the studied samples and the possibility of the occurrence of experimental errors, the approximations obtained are satisfactory;
- 4.
- By adding the RT recycled material, it was possible to demonstrate that the mixtures reached lower mechanical strengths as a function of due to the presence of brittle minerals in the RT that delayed the hydration of the cement and the early development of the hydrated calcium aluminates. In addition, there is an intimate relationship between the cementing agent content and the molding moisture content, which results in a negative impact when considering certain dosages, in all mechanical tests;
- 5.
- The RT-cement-soil compacted blends with a higher concentration ratio of cement and RT compositionally, show a higher content of aluminosilicates in the gel nanostructure and sodium cations, fulfilling the function of the network modifier (balance of charges) product of the substitution of the silicon for the tetrahedral aluminates. The preceding can be correlated with the best mechanical responses of these mixtures in the presence of an adequate content of RT, to optimize the soil-cement system;
- 6.
- Since the samples prepared for the split tensile strength are the same as those for the simple compressive strength test, the coefficient of determination shows the exact significance of the main effects. Furthermore, it was possible to obtain a direct correlation between these tests, which was demonstrated as the ratio between the tensile strength and the simple compressive strength (ξ = qt/qu). The value obtained was 0.18. The ratio ξ = qt/qu found a means that the tensile strength value by the diametral compression is equivalent to 18% of the simple compressive strength.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Physical Property of the Raw Material | Soil Results | RT Results |
---|---|---|
Liquid limit, % | 53.0 | - |
Plastic index, % | 21.4 | Non-Plastic |
Specific gravity | 2.72 | 2.38 |
Fine gravel (4.75–19 mm), % | - | 22.0 |
Coarse sand (2.0–4.75 mm), % | - | 17.0 |
Medium sand (0.425–2.0 mm), % | 7.45 | 12.0 |
Fine sand (0.075–0.425 mm), % | 25.88 | 8.0 |
Silt (0.002–0.075 mm), % | 57.59 | 29.0 |
Clay (diameter < 0.002 mm), % | 9.08 | 12.0 |
Medium diameter (D50), mm | 0.0245 | 0.20 |
USCS Classification | MH | - |
Chemical Compost | Concentration by Weight (%) |
---|---|
SiO2 | 52.22 |
Al2O3 | 23.15 |
Fe2O3 | 11.44 |
CaO | 0.04 |
MgO | 0.27 |
K2O | 0.38 |
Na2O | 0.03 |
TiO2 | 1.29 |
MnO | 0.19 |
P2O5 | 0.23 |
LOI | 10.76 |
Property | Value |
---|---|
Al2O3 (%) | 4.30 |
SiO2 (%) | 18.96 |
Fe2O3 (%) | 2.95 |
CaO (%) | 54.46 |
SO3 (%) | 2.54 |
MgO (%) | 3.68 |
The insoluble residue (in %) | 11.04 |
Axial resistance at seven days (MPa) | 20.1 |
Axial resistance at 28 days (MPa) | 41.2 |
The fineness of the cement particles (in %) | 1.82 |
The density of the cement particles | 3.15 |
Molding Point | ω | γd (kN/m3) | Saturation Degree |
---|---|---|---|
A1 | 0.25 | 15.0 | 0.85 |
A2 | 0.25 | 14.3 | 0.77 |
A3 | 0.25 | 13.7 | 0.70 |
A4 | 0.25 | 13.0 | 0.64 |
Spectrum/Area | Chemical Compositions (wt.%) | |||||||
---|---|---|---|---|---|---|---|---|
C | O | Al | Si | K | Ca | Ti | Fe | |
1 | - | 65.25 | 13.40 | 15.87 | 0.30 | 1.59 | 0.51 | 3.07 |
2 | 8.36 | 60.79 | 13.18 | 13.52 | 0.25 | 0.39 | 0.66 | 2.85 |
3 | 12.66 | 60.61 | 8.05 | 11.24 | 0.21 | 5.80 | 0.20 | 1.22 |
Maximum value | 12.66 | 65.25 | 13.40 | 15.87 | 0.30 | 5.80 | 0.66 | 3.07 |
Minimum value | 8.36 | 60.61 | 8.05 | 11.24 | 0.21 | 0.39 | 0.20 | 1.22 |
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Baldovino, J.A.; Millan-Paramo, C.; Saba, M. Porosity-to-Cement Index Controlling the Strength and Microstructure of Sustainable Crushed Material-Cemented Soil Blends. Buildings 2022, 12, 1966. https://doi.org/10.3390/buildings12111966
Baldovino JA, Millan-Paramo C, Saba M. Porosity-to-Cement Index Controlling the Strength and Microstructure of Sustainable Crushed Material-Cemented Soil Blends. Buildings. 2022; 12(11):1966. https://doi.org/10.3390/buildings12111966
Chicago/Turabian StyleBaldovino, Jair A., Carlos Millan-Paramo, and Manuel Saba. 2022. "Porosity-to-Cement Index Controlling the Strength and Microstructure of Sustainable Crushed Material-Cemented Soil Blends" Buildings 12, no. 11: 1966. https://doi.org/10.3390/buildings12111966