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ARTÍCULO
TITULO

Adsorptive Removal of Iron and Manganese from Groundwater Samples in Ghana by Zeolite Y Synthesized from Bauxite and Kaolin

Bright Kwakye-Awuah    
Baah Sefa-Ntiri    
Elizabeth Von-Kiti    
Isaac Nkrumah and Craig Williams    

Resumen

Ground water samples from residential homes in three Regions of Ghana: Central, Greater Accra and Ashanti, were analyzed for iron and manganese contamination. The samples were exposed to characterized zeolite Y by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, Fourier transformed-infrared spectroscopy and thermos gravimetric-differential thermal analysis. Zeolite Y is able to remove 98% of iron and 97% of manganese within an hour. The adsorption of both iron and manganese followed the Freundlich model, suggesting that the ions were transported onto the zeolite Y surface and subsequently diffused into the zeolite Y framework. The kinetic studies showed that pseudo-first order and intra particle and film diffusion models provided the best fit. The adsorption at 0.2 mg L-1 Fe (Q0.2" role="presentation">??0.2Q0.2 Q 0.2 ) is calculated to be 0.023 mg g-1 for the Freundlich adsorption model, whilst that of manganese at 0.05 mg L-1 Mn (Q0.05" role="presentation">??0.05Q0.05 Q 0.05 ) is evaluated to be 0.015 mg g-1. The zeolite retains its adsorption properties when retrieved from the first exposure water sample, washed copiously with distilled water and added to fresh water samples. The results suggest that zeolite Y can be used as a potential adsorbent for the removal of iron and manganese from groundwater.

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